This is a walkthrough for Route 210 (South), including what Pokémon you can encounter and items you can find.

How to Get Past the Psyduck Barricade

Halfway along the route, there’s a group of Psyduck blocking the way near the Café Cabin. To remove the Psyduck, you must use the Secret Medicine from Cynthia at Valor Lakefront.

To make Cynthia appear, you must obtain 4 Gym Badges and speak to the suspicious Galactic Grunt located in Pastoria City, near the Great Marsh entrance. When the Grunt runs away, chase him until he reaches Valor Lakefront (he will stop to rest every now and then).

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Pokémon Encounters

Wild Pokémon - Tall Grass

Pokémon	Type	Encounter Rate
Bonsly		25% (Morning), 5% (Day/Night) [Shining Pearl]
Chansey		5%
Geodude		30%
Kricketune		10% (Morning/Day), 30% (Night)
Mime Jr.		25% (Morning), 5% (Day/Night) [Brilliant Diamond]
Ponyta		30% (Morning/Night), 50% (Day)

Wild Pokémon - Poké Radar

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Pokémon	Type	Encounter Rate
Miltank		10% (Shining Pearl), 2% (Brilliant Diamond)
Tauros		10% (Brilliant Diamond), 2% (Shining Pearl)

Item Locations

Item	Location
TM51 Roost x3	Obtained from the girl south of the Honey Tree.
Great Ball	North of Pokémon Breeder Kahlil.
Great Ball (hidden)	In the middle of the grass patch nelow Café Cabin
Old Charm	Obtained from Cynthia after curing Psyduck.
Super Repel	Behind a tree, west of Psyduck.
Aspear Berry x4	Berry Patch near Celestic Town Entrance.
Razz Berry x2	Berry Patch near Celestic Town Entrance.
Pinap Berry x2	Berry Patch near Celestic Town Entrance.
Hyper Potion	In the middle of the grass patch.
Ultra Ball	Northwest corner of grass patch.